Start / All Programs / Accessories / Command Prompt
ipconfig /all
item Physical Address
Likely there will be more than one listed, so which? Exclude the ones under a heading that says wireless.
For the wired connector, you will see the text media disconnected, or not, depending on whether there’s a live cable plugged in when you run the command.
Finder / Applications / Utilities / Terminal.app
ifconfig en0
The third line reads something like
ether 01:23:45:67:89:ab
From www.mun.ca, search for wired network connections.
A.E. 2011.06.16